Editor at 00:00, 1 October 2008

2008-10-01T00:00:00Z

Editor at 00:00, 30 September 2008

2008-09-30T00:00:00Z

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{{Metabolite
|LipidBank=XPR8003
|LipidMaps=LMFA03120003
|SysName=methyl (4R,5E,7Z) -4-acetoxy-7- [ (S) -2-acetoxy-2- [ (Z) -2-octenyl ] -5-oxo-3-cyclopentenylidene ] -5-heptenoate
|Common Name=&&clavulone III<<8001/8003>>/claviridenone-b<<8002/8006>>&&
|Reflactive=[a]D +45.5°(C 0.22, CHCl3)<<8001>>
|Solubility=Clavulones are soluble in MeOH, EtOH, CHCl3, or hexane.
|UV Spectra=lmax(EtOH) 230 nm(e17200),295 nm(e17600)<<8022>>
|IR Spectra=nmax(film)1735,1690,1640,and 1230cm-1<<8022>>
|NMR Spectra=1H-NMR(270MHz,CDCl3)dppm0.88(3H,t,J=6.9Hz),2.04(3H,s),2.10(3H,s),2.39(2H,t,J=7.5Hz),2.66(1H,dd,J=7,14.5Hz),2.86(1H,dd,J=7,14.5Hz),3.67(3H,s),5.21(1H,dt,J=11,7Hz),5.52(1H,dt,J=11,8Hz),5.44(1H,q,J=6Hz),6.02(1H,dd,J=6,15.5Hz),6.36(1H,d,J=6.3Hz),6.52(1H,d,J=11.2Hz),7.50(1H,d,J=6.3Hz),7.74(1H,dd,J=11.2,15.5Hz).<<8001>>13C-NMR(67.8MHz,CDCl3)dppm14.0(q),21.0(q),21.7(q),22.5(t),27.4(t),29.1(t),29.2(t),29.8(t),31.5(t),35.6(t),51.7(q),72.5(d),85.3(s),121.4(d),126.5(d),133.4(d),134.8(d),135.7(s),141.0(d),156.1(d),169.7(s),170.1(s),173.1(s),194.1(s).<<8001>>
|NOTE Spectra=CDlext(EtOH)(De)nm 245(+3.4),297(-0.6).<<8022>>
}}

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LBF21406CV03 - Revision history

Editor at 00:00, 1 October 2008

Editor at 00:00, 30 September 2008