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Licoricesaponin L3 - Revision history
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Toyama: /* Spectroscopic Data */
2010-02-09T03:23:44Z
<p><span dir="auto"><span class="autocomment">Spectroscopic Data</span></span></p>
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<td colspan='2' style="background-color: white; color:black;">← Older revision</td>
<td colspan='2' style="background-color: white; color:black;">Revision as of 03:23, 9 February 2010</td>
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<tr><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div>| '''IR''' (KBr || 3650-3100 (br), 2912, 1704 (br), 1658, 1622, 1382, 1048 cm<sup>-1</sup></div></td><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div>| '''IR''' (KBr || 3650-3100 (br), 2912, 1704 (br), 1658, 1622, 1382, 1048 cm<sup>-1</sup></div></td></tr>
<tr><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div>|-</div></td><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div>|-</div></td></tr>
<tr><td class='diff-marker'>−</td><td style="background: #ffa; color:black; font-size: smaller;"><div>| '''<sup>1</sup>H-NMR''' (C<sub>5</sub>D<sub>5</sub>N+D<sub>2</sub>O, 500 MHz)|| 0.92 (s, <del class="diffchange diffchange-inline">CH3</del>), 0.93 (s, <del class="diffchange diffchange-inline">CH3</del>), 0.99 (s, <del class="diffchange diffchange-inline">CH3</del>), 1.32 (s, <del class="diffchange diffchange-inline">CH3</del>), 1.33 (s, <del class="diffchange diffchange-inline">CH3</del>), 1.44 (s, <del class="diffchange diffchange-inline">CH3</del>), 1.74 (d, ''J''=6.1 Hz, 3xH-6 of Rha), 2.02 (s, <del class="diffchange diffchange-inline">OCOCH3</del>), 3.42 (dd, ''J''=3.6, 12.0 Hz, H-3), 4.95 (d, ''J''=7.6 Hz, H-1 of GlcUA), 5.52 (d, ''J''=7.3 Hz, H-1 of  Ara), 5.54 (brs, H-12), 6.15 (brs, H-1 of Rha)</div></td><td class='diff-marker'>+</td><td style="background: #cfc; color:black; font-size: smaller;"><div>| '''<sup>1</sup>H-NMR''' (C<sub>5</sub>D<sub>5</sub>N+D<sub>2</sub>O, 500 MHz)|| 0.92 (s, <ins class="diffchange diffchange-inline">CH<sub>3</sub></ins>), 0.93 (s, <ins class="diffchange diffchange-inline">CH<sub>3</sub></ins>), 0.99 (s, <ins class="diffchange diffchange-inline">CH<sub>3</sub></ins>), 1.32 (s, <ins class="diffchange diffchange-inline">CH<sub>3</sub></ins>), 1.33 (s, <ins class="diffchange diffchange-inline">CH<sub>3</sub></ins>), 1.44 (s, <ins class="diffchange diffchange-inline">CH<sub>3</sub></ins>), 1.74 (d, ''J''=6.1 Hz, 3xH-6 of Rha), 2.02 (s, <ins class="diffchange diffchange-inline">OCOCH<sub>3</sub></ins>), 3.42 (dd, ''J''=3.6, 12.0 Hz, H-3), 4.95 (d, ''J''=7.6 Hz, H-1 of GlcUA), 5.52 (d, ''J''=7.3 Hz, H-1 of  Ara), 5.54 (brs, H-12), 6.15 (brs, H-1 of Rha)</div></td></tr>
<tr><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div>|-</div></td><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div>|-</div></td></tr>
<tr><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div>| '''<sup>13</sup>C-NMR''' (C<sub>5</sub>D<sub>5</sub>N+D<sub>2</sub>O, 125MHz)|| C-1) 38.7, (2) 26.3, (3) 91.0, (4) 44.0, (5) 56.1, (6) 18.8, (7) 32.9, (8) 40.1, (9) 47.7, (10) 36.2, (11) 24.0, (12) 124.7, (13) 144.1, (14) 41.9, (15) 26.6, (16) 27.8, (17) 37.5, (18) 44.2, (19) 40.8, (20) 29.8, (21) 41.7, (22) 78.1, (23) 22.9, (24) 63.4, (25) 15.7, (26)16.8, (27) 26.3, (28) 26.6, (29) 29.8, (30) 179.4 '''GlcUA''' (1) 105.4, (2) 78.1, (3) 75.8, (4) 72.6, (5) 77.6, (6) 172.2 '''Ara''' (1)102.2, (2) 78.1, (3) 76.7, (4) 70.7, (5) 66.8 '''Rha''' (1) 101.8, (2) 72.3, (3) 73.9, (4) 74.4, (5) 69.4, (6) 18.5   </div></td><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div>| '''<sup>13</sup>C-NMR''' (C<sub>5</sub>D<sub>5</sub>N+D<sub>2</sub>O, 125MHz)|| C-1) 38.7, (2) 26.3, (3) 91.0, (4) 44.0, (5) 56.1, (6) 18.8, (7) 32.9, (8) 40.1, (9) 47.7, (10) 36.2, (11) 24.0, (12) 124.7, (13) 144.1, (14) 41.9, (15) 26.6, (16) 27.8, (17) 37.5, (18) 44.2, (19) 40.8, (20) 29.8, (21) 41.7, (22) 78.1, (23) 22.9, (24) 63.4, (25) 15.7, (26)16.8, (27) 26.3, (28) 26.6, (29) 29.8, (30) 179.4 '''GlcUA''' (1) 105.4, (2) 78.1, (3) 75.8, (4) 72.6, (5) 77.6, (6) 172.2 '''Ara''' (1)102.2, (2) 78.1, (3) 76.7, (4) 70.7, (5) 66.8 '''Rha''' (1) 101.8, (2) 72.3, (3) 73.9, (4) 74.4, (5) 69.4, (6) 18.5   </div></td></tr>
<tr><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div>|}</div></td><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div>|}</div></td></tr>
<tr><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div><small>M. Yoshikawa et al., Chem.Pharm.Bull., 41, 1567 (1993).</small></div></td><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div><small>M. Yoshikawa et al., Chem.Pharm.Bull., 41, 1567 (1993).</small></div></td></tr>
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Toyama
http://metabolomics.jp/mediawiki/index.php?title=Licoricesaponin_L3&diff=107979&oldid=prev
Toyama: New page: {{Hierarchy|{{PAGENAME}}}} {{Metabolite |SysName=(3beta,4beta,20beta,22beta)-22-(Acetyloxy)-20-carboxy-23-hydroxy-30-norolean-12-en-3-yl O-6-deoxy-alpha-L-mannopyranosyl-(1-2)-O-alpha-L-a...
2010-02-09T02:22:47Z
<p>New page: {{Hierarchy|{{PAGENAME}}}} {{Metabolite |SysName=(3beta,4beta,20beta,22beta)-22-(Acetyloxy)-20-carboxy-23-hydroxy-30-norolean-12-en-3-yl O-6-deoxy-alpha-L-mannopyranosyl-(1-2)-O-alpha-L-a...</p>
<p><b>New page</b></p><div>{{Hierarchy|{{PAGENAME}}}}<br />
<br />
{{Metabolite<br />
|SysName=(3beta,4beta,20beta,22beta)-22-(Acetyloxy)-20-carboxy-23-hydroxy-30-norolean-12-en-3-yl O-6-deoxy-alpha-L-mannopyranosyl-(1-2)-O-alpha-L-arabinopyranosyl-(1-2)-beta-D-glucopyranosiduronic acid<br />
|Common Name=&&Licoricesaponin L3&&Saponin L3 from licorice&&30-Noroleanane beta-D-glucopyranosiduronic acid deriv.&&<br />
|CAS=156500-46-8<br />
|KNApSAcK=<br />
}}<br />
<br />
<br />
==Spectroscopic Data==<br />
<br />
{| class="wikitable" style="width:80%"<br />
|- <br />
| '''M.P.''' || 233 - 234 °C <br />
|- <br />
| '''IR''' (KBr || 3650-3100 (br), 2912, 1704 (br), 1658, 1622, 1382, 1048 cm<sup>-1</sup><br />
|-<br />
| '''<sup>1</sup>H-NMR''' (C<sub>5</sub>D<sub>5</sub>N+D<sub>2</sub>O, 500 MHz)|| 0.92 (s, CH3), 0.93 (s, CH3), 0.99 (s, CH3), 1.32 (s, CH3), 1.33 (s, CH3), 1.44 (s, CH3), 1.74 (d, ''J''=6.1 Hz, 3xH-6 of Rha), 2.02 (s, OCOCH3), 3.42 (dd, ''J''=3.6, 12.0 Hz, H-3), 4.95 (d, ''J''=7.6 Hz, H-1 of GlcUA), 5.52 (d, ''J''=7.3 Hz, H-1 of Ara), 5.54 (brs, H-12), 6.15 (brs, H-1 of Rha)<br />
|-<br />
| '''<sup>13</sup>C-NMR''' (C<sub>5</sub>D<sub>5</sub>N+D<sub>2</sub>O, 125MHz)|| C-1) 38.7, (2) 26.3, (3) 91.0, (4) 44.0, (5) 56.1, (6) 18.8, (7) 32.9, (8) 40.1, (9) 47.7, (10) 36.2, (11) 24.0, (12) 124.7, (13) 144.1, (14) 41.9, (15) 26.6, (16) 27.8, (17) 37.5, (18) 44.2, (19) 40.8, (20) 29.8, (21) 41.7, (22) 78.1, (23) 22.9, (24) 63.4, (25) 15.7, (26)16.8, (27) 26.3, (28) 26.6, (29) 29.8, (30) 179.4 '''GlcUA''' (1) 105.4, (2) 78.1, (3) 75.8, (4) 72.6, (5) 77.6, (6) 172.2 '''Ara''' (1)102.2, (2) 78.1, (3) 76.7, (4) 70.7, (5) 66.8 '''Rha''' (1) 101.8, (2) 72.3, (3) 73.9, (4) 74.4, (5) 69.4, (6) 18.5 <br />
|}<br />
<small>M. Yoshikawa et al., Chem.Pharm.Bull., 41, 1567 (1993).</small></div>
Toyama