View source for LBF21406CV01

{{Hierarchy|{{PAGENAME}}}}

{{Metabolite
|LipidBank=XPR8001
|LipidMaps=LMFA03120001
|SysName=methyl (4R,5Z,7E) -4-acetoxy-7- [ (S) -2-acetoxy-2- [ (Z) -2-octenyl ] -5-oxo-3-cyclopentenylidene ] -5-heptenoate
|Common Name=&&clavulone I<<8001/8003>>/claviridenone-d<<8002/8006>>&&
|Reflactive=[<FONT FACE="Symbol">a</FONT>]<SUB><FONT SIZE=-1>D</FONT></SUB> -28.9°(C 0.36, CHCl<SUB><FONT SIZE=-1>3</FONT></SUB>)<<8001>>
|Solubility=Clavulones are soluble in MeOH, EtOH, CHCl<SUB><FONT SIZE=-1>3</FONT></SUB> or hexane.
|UV Spectra=<FONT FACE="Symbol">l</FONT><SUB><FONT SIZE=-1>m</FONT></SUB><SUB><FONT SIZE=-1>a</FONT></SUB><SUB><FONT SIZE=-1>x</FONT></SUB>(EtOH) 230 nm(<FONT FACE="Symbol">e</FONT>13600),292 nm(<FONT FACE="Symbol">e</FONT>17300)<<8001>>
|IR Spectra=<FONT FACE="Symbol">n</FONT><SUB><FONT SIZE=-1>m</FONT></SUB><SUB><FONT SIZE=-1>a</FONT></SUB><SUB><FONT SIZE=-1>x</FONT></SUB>(film)1730,1700,1635,and 1230cm<SUP><FONT SIZE=-1>-</FONT></SUP><SUP><FONT SIZE=-1>1</FONT></SUP><<8001>>
|NMR Spectra=<SUP><FONT SIZE=-1>1</FONT></SUP>H-NMR(270MHz,CDCl<SUB><FONT SIZE=-1>3</FONT></SUB>)<FONT FACE="Symbol">d</FONT>ppm0.88(3H,t,J=6.7Hz),2.03(3H,s),2.05(3H,s),2.38(2H,t,J=7.7Hz),2.66(1H,dd,J=7,14.5Hz),2.97(1H,dd,J=7,14.5Hz),3.70(3H,s),5.22(1H,dt,J=10.9,7Hz),5.45(1H,dt,J=10.9,8Hz),5.78(1H,m),5.86(1H,t,J=10Hz),6.42(1H,d,J=6.3Hz),6.59(1H,dd,J=10,12.5Hz),7.25(1H,d,J=12.5Hz),7.47(1H,d,J=6.3Hz).<<8001>><SUP><FONT SIZE=-1>1</FONT></SUP><SUP><FONT SIZE=-1>3</FONT></SUP>C-NMR(67.8MHz,CDCl<SUB><FONT SIZE=-1>3</FONT></SUB>)<FONT FACE="Symbol">d</FONT>ppm14.0(q),20.9(q),21.2(q),22.5(t),27.4(t),29.0(t),29.8(t),29.8(t),31.4(t),35.9(t),51.7(q),69.4(d),85.2(s),121.0(d),124.3(d),124.4(d),134.9(d),137.5(s),138.7(d),157.8(d),169.0(s),169.7(s),172.7(s),193.0(s).<<8001>>
|NOTE Spectra=CD<FONT FACE="Symbol">l</FONT><SUB><FONT SIZE=-1>e</FONT></SUB><SUB><FONT SIZE=-1>x</FONT></SUB><SUB><FONT SIZE=-1>t</FONT></SUB>(EtOH)(<FONT FACE="Symbol">D</FONT><FONT FACE="Symbol">e</FONT>)nm 248(+3.8),291(-5.0).<<8022>>
}}