View source for LBF21406CV09

{{Hierarchy|{{PAGENAME}}}}

{{Metabolite
|LipidBank=XPR8009
|LipidMaps=LMFA03120009
|SysName=methyl (5E,7E) -7- [ (R) -4-chloro-2-hydroxy-2- [ (Z) -2-octenyl ] -5-oxo-3-cyclopentenylidene ] -5-heptenoate
|Common Name=&&chlorovulone II <<8025/8026>>&&
|Reflactive=[<FONT FACE="Symbol">a</FONT>]<SUB><FONT SIZE=-1>D</FONT></SUB> +22.7°(C 0.075, CHCl<SUB><FONT SIZE=-1>3</FONT></SUB>)<<8025>>
|Solubility=Chlorovulones are soluble in MeOH, EtOH, CHCl<SUB><FONT SIZE=-1>3</FONT></SUB>, or hexane.
|UV Spectra=<FONT FACE="Symbol">l</FONT><SUB><FONT SIZE=-1>m</FONT></SUB><SUB><FONT SIZE=-1>a</FONT></SUB><SUB><FONT SIZE=-1>x</FONT></SUB>(EtOH) 237 nm(<FONT FACE="Symbol">e</FONT>10000),312 nm(<FONT FACE="Symbol">e</FONT>10100)<<8025>>
|IR Spectra=<FONT FACE="Symbol">n</FONT><SUB><FONT SIZE=-1>m</FONT></SUB><SUB><FONT SIZE=-1>a</FONT></SUB><SUB><FONT SIZE=-1>x</FONT></SUB>(CHCl<SUB><FONT SIZE=-1>3</FONT></SUB>)3560,3300,1730,1705, and 1635cm<SUP><FONT SIZE=-1>-</FONT></SUP><SUP><FONT SIZE=-1>1</FONT></SUP>(Yamada Yasuji)
|NMR Spectra=<SUP><FONT SIZE=-1>1</FONT></SUP>H-NMR(400MHz,CDCl<SUB><FONT SIZE=-1>3</FONT></SUB>)<FONT FACE="Symbol">d</FONT>ppm0.88(3H,t,J=7.1Hz),1.30(6H,m),1.82(2H,quint.,J=7.4Hz),1.96(2H,brq,J=7.5Hz),2.30(2H,t,J=7.5Hz),2.35(2H,t,J=7.4Hz),2.68(1H,brdd,J=7.9,14.3Hz),2.81(1H,brdd,J=7.5,14.3Hz),3.67(3H,s),5.23(1H,ttd,J=1.4,7.7,10.9Hz),5.55(1H,brtd,J=7.5,10.9Hz),6.28(1H,td,J=7.4,15.1Hz),6.77(1H,tdd,J=1.3,11.9,15.1Hz),7.03(1H,d,J=11.9Hz),7.20(1H,s).<<8025>>
}}