Category:TP5

Revision as of 09:39, 12 December 2011

Sesquiterpene (C15)

Ring configuration

Germacrane

Sesquiterpenes

Biosynthesis

Overview

References

Sesquiterpene Synthase

farnesyl diphosphate
farnesyl cation
	farnesane, acyclic ones
	cyclobutane, cyclopentane
	cyclofarnesane
	germacrane (elemane, lepidozane, (bi)cyclogermacrane) [1] eudesmane (emmotin, oppositane, farfugin, cycloeudesmane, gorgonane, valerane/Jatamansane, spirovetivane (= vetispirane)) eremophilane (chiloscyphane, aristolane, nardosinane, brasilane (?), cacalol, page 133 fukinane Petasites japonicus, ishwarane guaiane (xanthane, carabrane, pseudoguaiane, cubebane, ivaxillarane, valerenane) cycloguaiane (aromadendrane, patchoulane, rotundane, bourbonane)
	humulane (caryyllophyllane, bicyclohumulane, africanane)
bisabolyl cation	bisabolane cuparane (herbertane liverwort,fungi, laurane Laurencia spp. (marine), cyclolaurane, trichothecane (from scirpane), gymnomitrane, thujopsane, widdrane, )
(Z,E)-germacradienyl cation	cadinane (bulgarane,calamenene, muurolane, amorphane, alliacane/primnatriene, oplopane, mutisianthol, cadalane, copaane)
(Z,E)-humulyl cation	himachalane (lippifoliane, longipinane, longibornane, longifolane)
	(proto)illudane (illudane, sterpurane, illudalane, isolactarane, merulane, lactarane, marasmane) --> hirsutane
cycloheptenyl cation	daucane (= carotane, isodaucane)
drimenyl cation	drimane (iresin, seco, coloratane)
furodysyl cation	furodysin (furodysinin)
chamigranyl cation	chamigrane (secochamigrane)
Others	pinguisane, picrotoxane, perforane, pacifigorgiane, asteriscane, botrydial Tricyclic Cedrane (isocedrane) Prezizaane (zizaane)