Category:TP5

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m (→‎{{Bilingual|セスキテルペン合成酵素|Sesquiterpene Synthase}})
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=={{Bilingual|生合成|Biosynthesis}}==
 
=={{Bilingual|生合成|Biosynthesis}}==
 
==={{Bilingual|概要|Overview}}===
 
==={{Bilingual|概要|Overview}}===
 +
Two major classes of terpene synthases exist: "transoid" and "cisoid" synthase.
 +
Transoid synthase directly ionizes ('trans','trans')-farnesyl diphosphate, whereas
 +
Cisoid synthase first isomerizes C2-C3 double bond to produce the neutral (3'R')- or (3'S')-nerolidyl diphosphate (enzyme-bound) and then ionizes it.
 +
 +
{|
 +
! Type || Substrate
 +
| Transoid synthase
 +
|(2-'trans',6-'trans')-farnesyl diphosphate
 +
|-
 +
| Cisoid synthase
 +
|((2-'cis',6-'trans')-farnesyl diphosphate
 +
|}
 +
  
  

Revision as of 09:58, 22 July 2014

Contents

Sesquiterpene (C15)

Ring configuration

Germacrane


Sesquiterpenes

Biosynthesis

Overview

Two major classes of terpene synthases exist: "transoid" and "cisoid" synthase. Transoid synthase directly ionizes ('trans','trans')-farnesyl diphosphate, whereas Cisoid synthase first isomerizes C2-C3 double bond to produce the neutral (3'R')- or (3'S')-nerolidyl diphosphate (enzyme-bound) and then ionizes it.

Type Substrate Transoid synthase (2-'trans',6-'trans')-farnesyl diphosphate
Cisoid synthase ((2-'cis',6-'trans')-farnesyl diphosphate


References


Sesquiterpene Synthase

farnesyl diphosphate
Farnesyl diphosphate.png
Arrow00d35.png
farnesyl cation
Farnesyl cation.png
farnesane, acyclic ones cyclobutane, cyclopentane cyclofarnesan
(E,E)-germacradiene
(E,E)-Germacradienyl cation.png
  • germacrane
    Germacrene A.png
  • lepidozane
    Lepidozane.png
  • bicyclogermacrane
    Bicyclogermacrane.png
eudesmane (= selinane)
Eudesmanyl cation.png
  • cycloeudesmane
    Cycloeudesmane.png
  • elemane ... 7,8 seco form
    Elemene.png
  • emmotin ... 14(10→1) abeo form
    Emmotin.png
  • farfugin ... 14(10→9) abeo form
    Farfugin.png
  • gorgonane 11(7→6) abeo form
    Gorgonane.png
  • oppositane ... 8(7→6) abeo form
    Oppositane.png
  • valerane (= jatamansane) 15(4→5) abeo form
    Valerane.png
vetispiradienyl cation
Vetispiradienyl cation.png
  • vetispiradiene
    Vetispiradiene.png
  • spirovetivane (= vetispirane)
    Spirovetivane.png
eremophilane (= 14(10→5) abeoeudesmane)
Eremophilenyl cation.png
  • aristolochene
    5-epi-Aristolochene.png
  • aristolane ... 6,11-cyclo form
    Aristolane.png
  • chiloscyphane ...8(7→6) abeo form
    Chiloscyphane.png
  • nardosinane ... 11(7→6) abeo form
    Nardosinane.png
  • cacalol ... 14(5→6) abeo form
    Cacalol.png
  • fukinane ... 9(8→7) abeo form
    Fukinane.png Petasites japonicus
  • brasilane
    Brasilane.png
  • thapsane
    Thapsane.png
  • ishwarane
    Ishwarane.png
guaiane
Guaiane.png
  • xanthane ... 4,5 seco form
    Xanthane.png
  • carabrane ... 4,5 seco form
    Carabrane.png
  • pseudoguaiane ... 15(4→5) abeo form
    Pseudoguaiane.png
  • valerenane ... 8(7→6) abeo form
    Valerenane.png

cycloguaiane

  • cubebane ... 1,6-cyclo form
    Cubebane.png
  • ivaxillarane ... 8,10-cyclo form
    Ivaxillarane.png
  • aromadendrane ... 6,11- cyclo form
    Aromadendrane.png
  • rotundane ... 10,12-cyclo form
    Rotundane.png
  • patchoulane ... 1,11-cyclo form
    Patchoulane.png
  • bourbonane ... 6,10-cyclo form
    Bourbonane.png
(E,E)-humulane
(E,E)-Humulyl cation.png
  • bicyclohumulane
    Bicyclohumulane.png
caryophyllane
(E)-beta-Caryophyllene.png
africanane
Africanane.png
drimane
Drimane.png
  • iresin
    Iresin.png
  • coloratane
    Coloratane.png
nerolidyl cation
Nerolidyl cation.png 		bisabolane
Bisabolyl cation.png
  • thujopsane
    (-)-Sesquithujene.png
chamigrane ... 6,11-cyclobisabolane
Chamigrane.png
  • acorane ... 6,10-cyclobisabolane
    Acorane.png
cuparane (= 7,11-cyclobisabolane)
Cuparane.png 		trichothecane [1]
Trichothecane.png
  • gymnomitrane
    Gymnomitrane.png
widdrane
(Z,E)-germacradiene
(Z,E)-Germacradienyl cation.png 		cadinane
Cadinane.png
  • muurolane
    Muurolane.png
  • bulgarane
    Bulgarane.png
  • amorphane
    Amorphane.png
  • calamenene
    Calamenene.png
  • cadalane
    Cadalane.png
  • alliacane ... 2(3→4) abeo cadinane
    Alliacane.png
  • primnatriene ... 2(3→4) abeo cadinane
    Primnatriene.png
  • oplopane ... 3(4→5) abeo cadinane
    Oplopane.png
  • mutisianthol ... 6(7→8) abeo cadinane
    Mutisianthol.png
  • copaane ... 5,10 cyclo cadinane
    Copaane.png
(Z,E)-humulane
(Z,E)-Humulyl cation.png 		himachalane
Himachalane.png
  • lippifoliane
    Lippifoliane.png
  • longipinane
    Longipinane.png
  • longibornane
    Longibornane.png
  • longifolane
    Longifolane.png
protoilludane
Protoilludane.png
  • illudane
    Illudane.png
  • illudalane ... 4,6-secoilludane
    Illudalane.png
  • sterpurane ... 5(6→7)-abeoilludane
    Sterpurane.png
  • isolactarane
    Isolactarane.png
  • merulane
    Merulane.png
  • lactarane
    Lactarane.png
  • marasmane
    Marasmane.png
hirsutane
Hirsutane.png
cycloheptenyl cation
Cycloheptenyl cation.png 		daucane (= carotane)
Daucane.png
  • isodaucane
    Isodaucane.png
furodysin
Furodysin.png
  • furodysinin
    Furodysinin.png
others
pinguisane
Pinguisane.png
picrotoxane
Picrotoxane.png
perforane
Perforane.png
pacifigorgiane
Pacifigorgiane.png
asteriscane
Asteriscane.png
botrydial
Botrydial.png
tricyclic
  • cedrane
    Cedrane.png
  • isocedrane
    Isocedrane.png
  • zizaane
    Zizaane.png
  • prezizaane
    Prezizaane.png
  • clovane
    Clovane.png
  • precapnellane
    Precapnellane.png
  • capnellane
    Capnellane.png
  • pentalenane
    Pentalenane.png
  • silphinane
    Silphinane.png
  • silphiperfoliane
    Silphiperfoliane.png
  • presilphiperfolane
    Presilphiperfolane.png
  • isocomane
    Isocomane.png
  • panasinsane
    Panasinsane.png
  • modhephane
    Modhephane.png
  • quadrane
    Quadrane.png
  • campherenane
    Campherenane.png
  • alpha-santalane
    Alpha-Santalane.png
  • beta-santalane
    Beta-Santalane.png
  • sativane
    Sativane.png
  • helminthosporane
    Helminthosporane.png
  • copacamphane
    Copacamphane.png
  • cyclocopacamphane
    Cyclocopacamphane.png
  • sinularane
    Sinularane.png
  • cyclosinularane
    Cyclosinularane.png

Cite error: <ref> tags exist, but no <references/> tag was found

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