Category:TP5

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Contents

Sesquiterpene (C15)

Ring configuration

Germacrane


Sesquiterpenes

Biosynthesis

Overview

References


Sesquiterpene Synthase

acorane
farnesyl diphosphate
Farnesyl diphosphate.png
Arrow00d35.png
farnesyl cation
Farnesyl cation.png
farnesane, acyclic ones cyclobutane, cyclopentane cyclofarnesane
(E,E)-germacradienyl cation
(E,E)-Germacradienyl cation.png
  • germacrene Germacrene A.png
  • elemene
  • lepidozene
  • bicyclogermacrene
eudesmanyl cation
Eudesmanyl cation.png
  • selinene Beta-Selinene.png
emmotin, oppositane, farfugin, cycloeudesmane, gorgonane, valerane/Jatamansane
vetispiradienyl_cation Vetispiradienyl cation.png spirovetivane (= vetispirane)
eremophilenyl cation
(1,2-CH3 shift from eudesmanyl cation)
Eremophilenyl cation.png

eremophilane (chiloscyphane, nardosinane, brasilane (?), cacalol, page 133 fukinane Petasites japonicus, ishwarane

  • eremophilene
  • aristolochene 5-epi-Aristolochene.png
guaiane (xanthane, carabrane, pseudoguaiane, cubebane, ivaxillarane, valerenane)
cycloguaiane (aromadendrane, patchoulane, rotundane, bourbonane)
(E,E)-humulyl cation
(E,E)-Humulyl cation.png 		humulane (caryyllophyllane, bicyclohumulane, africanane)
  • caryophyllene (E)-beta-Caryophyllene.png
nerolidyl cation
Nerolidyl cation.png 		bisabolyl cation
Bisabolyl cation.png 		bisabolane
cuparane (herbertane liverwort,fungi, laurane Laurencia spp. (marine), cyclolaurane, trichothecane (from scirpane), gymnomitrane thujopsane (-)-Sesquithujene.png widdrane
(Z,E)-germacradienyl cation
(Z,E)-Germacradienyl cation.png
cadinane (bulgarane,calamenene, muurolane, amorphane, alliacane/primnatriene, oplopane, mutisianthol, cadalane, copaane)
  • cadinene (+)-delta-Cadinene.png
(Z,E)-humulyl cation
(Z,E)-Humulyl cation.png 		himachalane (lippifoliane, longipinane, longibornane, longifolane)
  • longifolene (+)-Longifolene.png
(proto)illudane (illudane, sterpurane, illudalane, isolactarane, merulane, lactarane, marasmane) --> hirsutane
cycloheptenyl cation
Cycloheptenyl cation.png 		daucane (= carotane, isodaucane)
drimenyl cation drimane (iresin, seco, coloratane)
furodysyl cation furodysin (furodysinin)
chamigranyl cation chamigrane (secochamigrane)
Others
pinguisane, picrotoxane, perforane, pacifigorgiane, asteriscane, botrydial
Tricyclic
Cedrane (isocedrane)
Prezizaane (zizaane)


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