Enzyme:1.1.1.84

Upper Levels: EC1.-.-.- Oxidoreductases. : EC1.1.-.- Acting on the CH-OH group of donors. : EC1.1.1.- With NAD(+) or NADP(+) as acceptor.

IDs and Links
IUBMB	EC1
ExPaSy	NiceZyme 1.1.1.84

(R)-3,3-dimethylmalate:NAD+ oxidoreductase (decarboxylating)
Systematic Name	(R)-3,3-dimethylmalate:NAD+ oxidoreductase (decarboxylating)
Common Name	dimethylmalate dehydrogenase beta,beta-dimethylmalate dehydrogenase

NAD+ + (R)-3,3-Dimethyl-malic acid = NADH + 3-Methyl-2-oxo-butanoic acid + CO2 (links: NAD+ + (3R) -3-Hydroxy-2,2-dimethylbutanedioic acid = NADH + 3-Methyl-2-oxo-butanoic acid + CO2)

NAD+ <Mapping> AtomMap:BMCCPUAPt031$BMCCPUAPt032$0 NADH 1 ↔ 1 2 ↔ 2 3 ↔ 3 4 ↔ 4 5 ↔ 5 6 ↔ 6 7 ↔ 7 8 ↔ 8 9 ↔ 9 10 ↔ 10 11 ↔ 11 12 ↔ 12 13 ↔ 13 14 ↔ 14 15 ↔ 15 19 ↔ 19 20 ↔ 20 21 ↔ 21 22 ↔ 22 23 ↔ 23 24 ↔ 24 25 ↔ 25 26 ↔ 26 28 ↔ 28 29 ↔ 29 30 ↔ 30 31 ↔ 31 32 ↔ 32 (3R) -3-Hydroxy-2,2-dimethylbutanedioic acid <Mapping> AtomMap:BMFYB4DAr006$BMFYB4CAr010$0 3-Methyl-2-oxo-butanoic acid 1 ↔ 1 2 ↔ 2 3 ↔ 3 5 ↔ 5 6 ↔ 4 (3R) -3-Hydroxy-2,2-dimethylbutanedioic acid <Mapping> AtomMap:BMFYB4DAr006$BMXXSX--0007$0 CO2 4 ↔ 1