Doc:FL63AG
From Metabolomics.JP
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Gallocatechins refer to a subgroup of Flavan 3-ol derivatives (FL63AG). Compared to catechins, they have an additional phenolic hydroxyl group. Catechin gallates are gallic acid esters of the catechins, and (-)-Epigallocatechin gallate (EGCG) is the most abundant catechin in green tea but not in black tea. |
ガロカテキン類はFlavan 3-olの下にあるグループで、カテキン類のフェノール部に水酸基が1つ追加されたものです。カテキンガレートは、カテキンが没食子酸とエステル結合したもので、(-)-Epigallocatechin gallate (EGCG)は緑茶中に最も多いカテキンですが、紅茶には含まれません。(詳細) |
| Structure | |
|
|
|---|---|---|---|
| Name | (+)-Gallocatechin or D-Gallocatechin; GC |
(-)-Epigallocatechin or L-Epigallocatechin; EGC |
(-)-Gallocatechin or L-Gallocatechin |
| B-ring stereo | ↓ | ↓ | ↑ |
| 3-Hydroxyl stereo | ↑ | ↓ | ↓ |
| Gallate form | |
|
|
| (+)-Gallocatechin gallate or GCG | (-)-Epigallocatechin gallate or EGCG | (-)-Gallocatechin gallate | |
| B-ring stereo | ↓ | ↓ | ↑ |
| 3-Hydroxyl stereo | ↑ | ↓ | ↓ |
| Catechins | (+)-Catechin | (-)-Epicatechin | ent-Catechin |